I have to explain my situation a little better.
At my mobile I'm logged in windows mobile messenger with private live account x.
At my desktop at work I want to be logged in in a webmessenger(since client version ain't available) with my business live account y.
With the old MSN webmessenger I was able to login this messenger with account y and whenerver I wanted to login live.com with my private live mail account x simultanious. Since the integration of live.com with webmessenger this is not possible anymore with Microsoft products.
I found a kind of workaround with MSN2Go, but rather use real Microsoft product(s).
I have to say that I really don't like the integration, because the contact list is a bulky live.com browser window instead of a slim contact list with online buddies as in the client version.